What's the difference between Photon server and Photon Pun

I was looking at the pricings for photon pun and photon server and I noticed that there are price differences. If I were to use photon pun networking to make my game could I then host 100 CCU for free using the photon server pricing.
I suspect the answer is obviously no but I would like an explanation because I don't really understand why.

Thanks

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